人才队伍
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人才信息
姓名:
 李兴伟
性别:
 男
类别:
 研究员;杰出青年;百人
学科:
 无
职称:
 研究员
学历:
 博士研究生
电话:
 0411-84379089
Email:
 xwli@dicp.ac.cn
地址:
 辽宁省大连市中山路457号
邮编:
 116023
简历介绍:

李兴伟,1996年本科毕业于复旦大学化学系,2005年获美国耶鲁大学化学系博士学位,并获得耶鲁大学该年度Richard Wolfgang 最佳(化学)博士论文奖。2005-2006年在美国加州理工学院John Bercaw实验室从事博士后研究工作。2006-2008年任新加坡南洋理工大学助理教授。2008-2009年在美国Scripps研究所任催化领域助理教授,2010年3月作为“百人计划”引进到所工作,担任创新特区研究组组长,2011年获中国科学院“百人计划”择优支持。主要从事金属有机合成及其反应机理以及以能源和方法学为导向的催化反应(如C-H及C-C键的活化及选择性氧化)研究,在发展金属-(杂环)卡宾键化学方面有丰富的经验积累。

研究方向:
职务:
社会任职:
获奖及荣誉:
代表论著:

1.   Li, X.; Incarvito, C. D.; Crabtree, R. H. “A Rare h2-Butadienyl Complex from an Alkyne Double Insertion with Double Vinylidene Rearrangement,” J. Am. Chem. Soc., 2003, 125, 3698-3699.

2.   Li, X.; Appelhans, L. N.; Faller, J. W.; Crabtree, R. H. “Stoichiometric C-C Coupling Reactions in the Coordination Sphere of an Iridium(III) Alkyl,” Organometallics 2004, 23, 3378-3387.

3. Chianese, A. R.; Li, X.; Janzen, M. C.; Faller, J. W.; Crabtree, R. H. “Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics,”.  Organometallics 2003, 22, 1663-1667.

4.Li, X.; Vogel, T.; Incarvito, C. D.; Crabtree, R. H. “Electronic and Steric Effects in the Insertion of Alkyns into Iridium Hydrides,” Organometallics 2005, 24, 62-76.

5. Li, X.; Incarvito, C. D.; Vogel, T.; Crabtree, R. H.“Intramolecular Oxygen Transfer from Nitro Groups to CºC bonds Mediated by Iridium Hydrides,” Organometallics 2005, 24, 3066-3073.

6.Li, X.; Chen, P.; Faller, J. W.; and Crabtree R. H. “Cycloiridation of Unsaturated Ketones, Esters and Acetophenones”, Organometallics 2005, 24, 4810-4815.

7.Li, X.; Chianese, A. R.; Vogel, T.; Crabtree, R. H. “Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides,” Org. Lett. 2005, 7, 5437-5440.

8.Bercaw, J. E.; Diaconescu, P. L.; Grubbs, R. H.; Kay, R. D.; Labinger, J. A., Li, X., Mehrkhodavandi, P. M.; Morris, G. E.; Sunley, G. J.; Vagner, P. (authors in alphabetical order) “On the Mechanism of the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide” J. Org. Chem. 2006, 71, 8907.

9.Bercaw, J. E.; Grubbs, R. H.; Hazari, N.; Labinger, J. A.; Li, X. (authors in alphabetical order) “Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid”, Chem. Commun. 2007, 2974.

10.Wang, X.; Chen, H.; Li, X.* “Ir(III)-induced C-bound to N-bound Tautomerization of an N-Heterocyclic Carbene”, Organometallics 2007, 26, 4684.

11.Song, G.; Wang, X., Li. Y. and Li. X.* “Iridium Hydrides with Abnormal N-Heterocyclic Carbenes via Highly Selective C-H Activation”, Organometallics, 2008, 27, 1187.

12.Song, G.; Zhang, Y. and Li, X.* “Rh and Ir Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine”, Organometallics 2008, 27, 1936.

13. Liu, X.*; Le, T. N.; Lu, Y.; Xiao, Y.; Ma, J.; Li, X. “An efficient synthesis of chiral phosphinyl oxide pyrrolidines and their application to asymmetric direct aldol reactions” Liu, X.; Le, T. N.; Lu, Y.; Xiao, Y.; Ma, J.; Li, X. Org. Bimolecular Chem. 2008, 6, 3997.

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